- CasNo92-06-8
- Purity99%
Location:Home > Pharmaceutical
1,3-Diphenylbenzene Good Manufacturer supply High Quality 92-06-8
- Molecular Formula:C18H14
- Molecular Weight:230.309
- Appearance/Colour:Yellow solid
- Melting Point:84-88 °C(lit.)
- Refractive Index:1.5681 (estimate)
- Boiling Point:379 °C(lit.)
- Flash Point:191°C
- PSA:0.00000
- Density:1.2 g/cm3
- LogP:5.02060
1,3-Diphenylbenzene(Cas 92-06-8) Usage
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Synthesis Reference(s) |
The Journal of Organic Chemistry, 51, p. 3162, 1986 DOI: 10.1021/jo00366a016 |
|
Reactivity Profile |
1,3-Diphenylbenzene is non-flammable but combustible (flash point 403°F). Extremely stable thermally. Incompatible with strong oxidizing agents but not very reactive at room conditions. |
|
Hazard |
Moderately toxic by ingestion. Combustible. Eye and upper respiratory tract irritant. |
|
Purification Methods |
Purify it as for o-terphenyl above. [Beilstein 5 IV 2480.] |
|
General Description |
Yellow solid. Mp 86-87°C; bp: 365°C. Density: 1.195 g cm-3. Insoluble in water. Usually shipped as a solid mixture with its isomers o-terphenyl and p-terphenyl that is used as a heat-transfer fluid. |
InChI:InChI=1/C18H14/c1-3-8-15(9-4-1)17-12-7-13-18(14-17)16-10-5-2-6-11-16/h1-14H
92-06-8 Relevant articles
Single electron transfer reductive cleavage of the aryl-nitrogen bond in phenyl-substituted dimethylanilines
Azzena,Dessanti,Melloni,Pisano
, p. 8291 - 8293 (1999)
By treatment with Li metal in THF at roo...
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Downes et al.
, p. 3454,3467 (1950)
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A straightforward synthesis of 4,5-dihalofunctionalized imidazol-2-ylidene/imidazolyl-metal complexes from trihaloimidazolium salts/imidazoles: Structure and catalytic studies
Avinash, Iruthayaraj,Gupta, Vivek,Karthik, Vedhagiri,Anantharaman, Ganapathi
, p. 104 - 114 (2017)
Backbone dihalofunctionalized imidazol-2...
Nickel(II) benzimidazolin-2-ylidene complexes with thioether-functionalized side chains as catalysts for Suzuki-Miyaura cross-coupling
Bernhammer, Jan C.,Huynh, Han Vinh
, p. 5845 - 5851 (2014)
Four bis(benzimidazolin-2-ylidene) nicke...
Suzuki cross-coupling of hexachlorobenzene promoted by the Buchwald ligands
Burukin, A. S.,Vasil’ev, A. A.,Zhdankina, G. M.,Zlotin, S. G.
, p. 169 - 172 (2022/02/17)
The study of cross-coupling between hexa...
Copper-catalyzed meta-selective arylation of phenol derivatives: An easy access to m-aryl phenols
Maraswami, Manikantha,Hirao, Hajime,Loh, Teck-Peng
, p. 2302 - 2309 (2021/02/20)
Achieving selective meta-functionalizati...
PRODUCTION METHOD OF COUPLING COMPOUND
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Paragraph 0069-0070, (2021/05/05)
PROBLEM TO BE SOLVED: To provide a produ...
Buchwald ligand-assisted Suzuki cross-coupling of polychlorobenzenes
Burukin, Alexander S.,Vasil'ev, Andrei A.,Zhdankina, Galina M.,Zlotin, Sergei G.
, p. 400 - 402 (2021/06/07)
Screening of four Buchwald ligands for t...
92-06-8 Process route
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100-25-4
para-dinitrobenzene
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-
71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1
benzene
-
-
92-52-4,1594-86-1
biphenyl
-
-
92-06-8
1,3-diphenylbenzene
-
-
84-15-1
o-terphenyl
-
-
92-93-3
1-phenyl-4-nitrobenzene
-
-
100-01-6,104810-17-5
4-nitro-aniline
-
-
730-40-5
disperse orange 3
| Conditions | Yield |
|---|---|
|
at 343 ℃;
Product distribution;
Mechanism;
thermolysis in supercritical benzene; other temperature, pressure;
|
100.0 (unit not given) 43.2 (unit not given) 25.5 (unit not given) 10.6 (unit not given) 6.8 (unit not given) 4.2 (unit not given) |
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-
1706-50-9
perhydro-meta-terphenyl
-
-
92-06-8
1,3-diphenylbenzene
-
-
4016-06-2
1,3-dicyclohexylbenzene
-
-
1667-08-9
1,3-diphenyl-cyclohexane
-
-
1973-15-5
3-cyclohexyl-1,1'-biphenyl
-
-
1333-74-0
hydrogen
| Conditions | Yield |
|---|---|
|
With
platinum on carbon;
at 90 - 95 ℃;
for 25h;
Time;
Flow reactor;
|
92-06-8 Upstream products
-
110-89-4
piperidine
-
60-29-7
diethyl ether
-
591-51-5
phenyllithium
-
2051-62-9
4'-biphenyl chloride
92-06-8 Downstream products
-
92-94-4
[1,1';4',1'']terphenyl
-
1706-50-9
perhydro-meta-terphenyl
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60631-83-6
4’-Bromo-[1,1’:3’,1”]terphenyl
-
133476-13-8
benzo
thieno<2,3-b>dibenzothiophene-3,9-disulfonic acid 5,5,7,7-tetraoxide
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