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1,3-Diphenylbenzene


  • CasNo92-06-8
  • Purity99%
Inquery

1,3-Diphenylbenzene Good Manufacturer supply High Quality 92-06-8

  • Molecular Formula:C18H14
  • Molecular Weight:230.309
  • Appearance/Colour:Yellow solid 
  • Melting Point:84-88 °C(lit.) 
  • Refractive Index:1.5681 (estimate) 
  • Boiling Point:379 °C(lit.) 
  • Flash Point:191°C 
  • PSA:0.00000 
  • Density:1.2 g/cm3 
  • LogP:5.02060 

1,3-Diphenylbenzene(Cas 92-06-8) Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 51, p. 3162, 1986 DOI: 10.1021/jo00366a016

Reactivity Profile

1,3-Diphenylbenzene is non-flammable but combustible (flash point 403°F). Extremely stable thermally. Incompatible with strong oxidizing agents but not very reactive at room conditions.

Hazard

Moderately toxic by ingestion. Combustible. Eye and upper respiratory tract irritant.

Purification Methods

Purify it as for o-terphenyl above. [Beilstein 5 IV 2480.]

General Description

Yellow solid. Mp 86-87°C; bp: 365°C. Density: 1.195 g cm-3. Insoluble in water. Usually shipped as a solid mixture with its isomers o-terphenyl and p-terphenyl that is used as a heat-transfer fluid.

InChI:InChI=1/C18H14/c1-3-8-15(9-4-1)17-12-7-13-18(14-17)16-10-5-2-6-11-16/h1-14H

92-06-8 Relevant articles

Single electron transfer reductive cleavage of the aryl-nitrogen bond in phenyl-substituted dimethylanilines

Azzena,Dessanti,Melloni,Pisano

, p. 8291 - 8293 (1999)

By treatment with Li metal in THF at roo...

-

Downes et al.

, p. 3454,3467 (1950)

-

A straightforward synthesis of 4,5-dihalofunctionalized imidazol-2-ylidene/imidazolyl-metal complexes from trihaloimidazolium salts/imidazoles: Structure and catalytic studies

Avinash, Iruthayaraj,Gupta, Vivek,Karthik, Vedhagiri,Anantharaman, Ganapathi

, p. 104 - 114 (2017)

Backbone dihalofunctionalized imidazol-2...

Nickel(II) benzimidazolin-2-ylidene complexes with thioether-functionalized side chains as catalysts for Suzuki-Miyaura cross-coupling

Bernhammer, Jan C.,Huynh, Han Vinh

, p. 5845 - 5851 (2014)

Four bis(benzimidazolin-2-ylidene) nicke...

Suzuki cross-coupling of hexachlorobenzene promoted by the Buchwald ligands

Burukin, A. S.,Vasil’ev, A. A.,Zhdankina, G. M.,Zlotin, S. G.

, p. 169 - 172 (2022/02/17)

The study of cross-coupling between hexa...

Copper-catalyzed meta-selective arylation of phenol derivatives: An easy access to m-aryl phenols

Maraswami, Manikantha,Hirao, Hajime,Loh, Teck-Peng

, p. 2302 - 2309 (2021/02/20)

Achieving selective meta-functionalizati...

PRODUCTION METHOD OF COUPLING COMPOUND

-

Paragraph 0069-0070, (2021/05/05)

PROBLEM TO BE SOLVED: To provide a produ...

Buchwald ligand-assisted Suzuki cross-coupling of polychlorobenzenes

Burukin, Alexander S.,Vasil'ev, Andrei A.,Zhdankina, Galina M.,Zlotin, Sergei G.

, p. 400 - 402 (2021/06/07)

Screening of four Buchwald ligands for t...

92-06-8 Process route

para-dinitrobenzene
100-25-4

para-dinitrobenzene

benzene
71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1

benzene

biphenyl
92-52-4,1594-86-1

biphenyl

1,3-diphenylbenzene
92-06-8

1,3-diphenylbenzene

o-terphenyl
84-15-1

o-terphenyl

1-phenyl-4-nitrobenzene
92-93-3

1-phenyl-4-nitrobenzene

4-nitro-aniline
100-01-6,104810-17-5

4-nitro-aniline

disperse orange 3
730-40-5

disperse orange 3

Conditions
Conditions Yield
at 343 ℃; Product distribution; Mechanism; thermolysis in supercritical benzene; other temperature, pressure;
100.0 (unit not given)
43.2 (unit not given)
25.5 (unit not given)
10.6 (unit not given)
6.8 (unit not given)
4.2 (unit not given)
perhydro-meta-terphenyl
1706-50-9

perhydro-meta-terphenyl

1,3-diphenylbenzene
92-06-8

1,3-diphenylbenzene

1,3-dicyclohexylbenzene
4016-06-2

1,3-dicyclohexylbenzene

1,3-diphenyl-cyclohexane
1667-08-9

1,3-diphenyl-cyclohexane

3-cyclohexyl-1,1'-biphenyl
1973-15-5

3-cyclohexyl-1,1'-biphenyl

hydrogen
1333-74-0

hydrogen

Conditions
Conditions Yield
With platinum on carbon; at 90 - 95 ℃; for 25h; Time; Flow reactor;

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